Bimetallic Co-Re/TiO2 catalysts were developed for efficient citral hydrogenation. Bimetallic catalysts were prepared by co-impregnation (CI), successive-impregnation (SI), and surface redox method (SR). The arrangement between the Co and Re species on these systems was fully characterized using several techniques (TEM-energy-dispersive X-ray spectroscopy, H2 temperature-programmed reduction, temperature-programmed desorption, XRD, CO FTIR spectroscopy, model reaction of cyclohexane dehydrogenation), and their catalytic performances were evaluated for the selective hydrogenation of citral towards unsaturated alcohols. The Re and Co species are completely isolated in the CI sample, presenting a very limited Co-Re interaction. In SI samples, the metals coexist in a Janus-type structure with a concentration of Re around Co. Decoration/core-shell structures are observed for SR samples resulting from the redox exchange between the metallic surface of the parent Co/TiO2 catalyst and the Re7+ species of the modifier precursor salt. The contact degree between the two metals gradually increases as follows: Isolated structure (CI)<Janus-type structure(SI)<decoration/core-shell structure (SR). The unchanging structure of all SI samples independent of the Re loading leads to similar electron transfer, and the increase in Re content results in agglomeration of Re, thus decreasing the catalytic activity. Density-of-state (DOS) calculations prove that the high valence of Re is a disadvantage for the hydrogenation reaction. For SR samples, the increase of Re loading contributes to the electron transfer from Re to Co that is consistent with a change of structure from decoration to core-shell. The lack of directly accessible Co atoms for SR catalysts with fully coated structure decreases the efficiency of Re reduction. The presence of Co-Re interaction resulting from the close contact between metals plays a dominant role in the hydrogenation of citral. Nevertheless, an excessively high contact degree is unnecessary for citral hydrogenation once Co-Re interaction has formed.
This research examined the distribution features of red beds and 1,100 Danxia landform sites across China, while probing the relationship between these spatial patterns and geological elements. This study is based on geological and tectonic maps of China. ArcGIS software was used to process the adjacent index, then perform a spatial analysis of Danxia landforms and red beds, and a coupling analysis of Danxia landforms and red beds with tectonics. Based on a point pattern analysis of Danxia landforms, the adjacent index is 0.31, and the coefficient of variation verified by Thiessen polygon reaches 449%. These figures reflect the clustered distribution pattern of the Danxia landforms. Across the country, Danxia landforms are concentrated into three areas, namely, the Southeast China region, the Sichuan Basin region and the Qilian-Liupan region. The exposure of red beds covers 9.16 × 105 km2, which accounts for 9.5% of the total land area of China. With this research background, the geological elements of tectonics and their effects on the distribution, number, and spatial pattern of Danxia landforms and red beds were analyzed.
Ionizing radiation is a recognized genotoxic agent, however, little is known about the role of the functional form of DNA in these processes. Post translational modifications on histone proteins control the organization of chromatin and hence control transcriptional responses that ultimately affect the phenotype. The purpose of this study was to investigate effects on chromatin caused by ionizing radiation in fish. Direct exposure of zebrafish (Danio rerio) embryos to gamma radiation (10.9 mGy/h for 3h) induced hyper-enrichment of H3K4me3 at the genes hnf4a, gmnn and vegfab. A similar relative hyper-enrichment was seen at the hnf4a loci of irradiated Atlantic salmon (Salmo salar) embryos (30 mGy/h for 10 days). At the selected genes in ovaries of adult zebrafish irradiated during gametogenesis (8.7 and 53 mGy/h for 27 days), a reduced enrichment of H3K4me3 was observed, which was correlated with reduced levels of histone H3 was observed. F1 embryos of the exposed parents showed hyper-methylation of H3K4me3, H3K9me3 and H3K27me3 on the same three loci, while these differences were almost negligible in F2 embryos. Our results from three selected loci suggest that ionizing radiation can affect chromatin structure and organization, and that these changes can be detected in F1 offspring, but not in subsequent generations.
The aim of this study is to explore the outcome of Teucrium polium (TP) medicinal plant consumption on the early stage of fetal development. We used the chicken embryo at 3 days of incubation as a model to evaluate the effect of TP plant extract during embryogenesis. In addition, quantitative polymerase chain reaction (qPCR) was applied to explore the expression of six genes related to cell proliferation, apoptosis, sur-vival, angiogenesis, and migration. Our data revealed that TP exposure inhibits angiogenesis of the chicken embryo and its chorioallantoic membrane. In addition, we found that TP extract significantly harms the normal development of the embryos since around 95% of TP-exposed embryos died after 1-3 days of treatment. Macroscopic examination did not show any anomalies in these embryos. However, qPCR analysis of activation transcription factor-3, B-cell lymphoma-2, caspase 8, inhibin subunit beta A, vascular endothelial growth factor-C, and Cadherin-6 type-2 genes revealed that these genes are considerably deregulated in heart and brain tissues from TP-exposed embryos in comparison with their matched tissues from unexposed ones. Our study implies that TP plant can have very toxic effects on the early stage of the embryo. Therefore, it is important to alert expectant women to avoid the use of this medicinal plant during pregnancy.
ABSTRACT Diaspora actors demonstrate their ability to play a role in a variety of political and social processes in their homelands, including transitional justice. Transnational diaspora memorialization initiatives have become embedded and sustained within different contexts. This paper examines how the causal mechanism of coordination affects memorialization initiatives. It compares memorialization efforts in two localities in Bosnia and Herzegovina with different levels of coordination between diaspora, returnees, and local institutional actors. Centralized coordination with the help of a homeland institution enriches existing memory narratives and aims to forward transitional justice. Memorialization and commemorative practices initiated by diaspora without homeland institutional backing can lead to coordination among a more diverse set of actors, ultimately fostering new, alternative, and more inclusive memory narratives.
A major challenge in atomic force microscopy is to reduce the scan duration while retaining the image quality. Conventionally, the scan rate is restricted to a sufficiently small value in order to ensure a desirable image quality as well as a safe tip–sample contact force. This usually results in a conservative scan rate for samples that have a large variation in aspect ratio and/or for scan patterns that have a varying linear velocity. In this paper, an adaptive scan scheme is proposed to alleviate this problem. A scan line-based performance metric balancing both imaging speed and accuracy is proposed, and the scan rate is adapted such that the metric is optimized online in the presence of aspect ratio and/or linear velocity variations. The online optimization is achieved using an extremum-seeking approach, and a semiglobal practical asymptotic stability result is shown for the overall system. Finally, the proposed scheme is demonstrated via both simulation and experiment.
The first objective of this study was to examine whether there are achievement goal orientation profile differences regarding enjoyment of swimming. The second objective was to assess which sources of enjoyment differentiate swimmers of different achievement goal orientation profiles. Female (N=128) and male (N=174) swimmers aged 10 to 18 years completed questionnaires of swimming enjoyment, sources of enjoyment in sport (SEYSQ), and achievement goal orientation (TEOSQ). ANOVA revealed that those with high task/high ego, high task/moderate ego and moderate task/low ego profiles have significantly higher levels of enjoyment of swimming as compared to those with low task/moderate ego profiles. Discriminant analysis showed that four groups of swimmers could be described by two discriminant functions. High task/high ego group is placed on the positive side of the function “achievement with intrinsic motivation”. This group Original Research Article Šilić et al.; JESBS, 28(4): 1-12, 2018; Article no.JESBS.46615 2 showed greatest enjoyment of swimming in other-referenced competency and recognition, effort expenditure, self-referenced competency, positive parental involvement and competitive excitement. Low task/moderate ego group significantly stands out on the positive side of the “achievement without effort” function and showed greatest enjoyment only in other-referenced competency and recognition. This research serves as a step towards a better understanding of a conceptual link between goal orientation and sources of enjoyment in young swimmers.
Aims The aim of this study was to determine whether the Joint European Societies guidelines on secondary cardiovascular prevention are followed in everyday practice. Design A cross-sectional ESC-EORP survey (EUROASPIRE V) at 131 centres in 81 regions in 27 countries. Methods Patients (<80 years old) with verified coronary artery events or interventions were interviewed and examined ≥6 months later. Results A total of 8261 patients (females 26%) were interviewed. Nineteen per cent smoked and 55% of them were persistent smokers, 38% were obese (body mass index ≥30 kg/m2), 59% were centrally obese (waist circumference: men ≥102 cm; women ≥88 cm) while 66% were physically active <30 min 5 times/week. Forty-two per cent had a blood pressure ≥140/90 mmHg (≥140/85 if diabetic), 71% had low-density lipoprotein cholesterol ≥1.8 mmol/L (≥70 mg/dL) and 29% reported having diabetes. Cardioprotective medication was: anti-platelets 93%, beta-blockers 81%, angiotensin-converting enzyme inhibitors/angiotensin receptor blockers 75% and statins 80%. Conclusion A large majority of coronary patients have unhealthy lifestyles in terms of smoking, diet and sedentary behaviour, which adversely impacts major cardiovascular risk factors. A majority did not achieve their blood pressure, low-density lipoprotein cholesterol and glucose targets. Cardiovascular prevention requires modern preventive cardiology programmes delivered by interdisciplinary teams of healthcare professionals addressing all aspects of lifestyle and risk factor management, in order to reduce the risk of recurrent cardiovascular events.
The Editors’ Network of the European Society of Cardiology (ESC) provides a dynamic forum for editorial discussions and endorses the recommendations of the International Committee of Medical Journal Editors (ICMJE) to improve the scientific quality of biomedical journals. Authorship confers credit and important academic rewards. Recently, however, the ICMJE emphasised that authorship also requires responsibility and accountability. These issues are now covered by the new (fourth) criterion for authorship. Authors should agree to be accountable and ensure that questions regarding the accuracy and integrity of the entire work will be appropriately addressed. This review discusses the implications of this paradigm shift on authorship requirements with the aim of increasing awareness of good scientific and editorial practices.
Objetivo: identificar, na literatura científica nacional, a assistência de enfermagem na prevenção da violência obstétrica. Metodologia: revisão integrativa da literatura, realizada entre os meses de maio a junho de 2017, nas bases de dados online Scientific Electronic Library Online (SciELO) e na Literatura Latino-Americana e do Caribe em Ciências da Saúde (LILACS). Foram detectados 30 artigos sendo utilizados 09 artigos. Resultados: após a leitura e análise dos artigos, surgiram as seguintes categorias temáticas: Medidas de prevenção a violência obstétrica; Experiências com a prevenção da violência obstétrica e Conhecendo os fatores de risco para a violência obstétrica. O enfermeiro buscar em sua assistência o vínculo com a parturiente para proporcionar um parto saudável, evitando assim a violência obstétrica. Conclusão: Para prevenir a violência obstétrica fazse necessário uma assistência de enfermagem e um ambiente que proporcionem a autonomia da mulher gestante.Descritores: Violência; Gravidez; Assistência de Enfermagem.NURSING CARE IN THE PREVENTION OF OBSTETRIC VIOLENCEObjective: to identify, in the national scientific literature, nursing care in the prevention of obstetric violence. Methodology: integrative review of the literature, conducted between May and June 2017, in the online databases Scientific Electronic Library Online (SciELO) and in the Latin American and Caribbean Literature in Health Sciences (LILACS). There were 30 articles and 09 articles were used. Results: after reading and analyzing the articles, the following thematic categories emerged: Obstetric violence prevention measures; Experiences with the prevention of obstetric violence and Knowing the risk factors for obstetric violence. The nurse seeks in her assistance the bond with the parturient to provide a healthy delivery, thus avoiding obstetric violence. Conclusion: To prevent obstetric violence, it is necessary to provide nursing care and an environment that provides the autonomy of pregnant women.Descriptors: Violence; Pregnancy; Nursing Care.CUIDADOS DE ENFERMERÍA EN LA PREVENCIÓN DE LA VIOLENCIA OBSTÉTRICAObjetivo: identificar, en la literatura científica nacional, la asistencia de enfermería en la prevención de la violencia obstétrica. Metodología: revisión integrativa de la literatura, realizada entre los meses de mayo a junio de 2017, en las bases de datos online Scientific Electronic Library Online (SciELO) y en la Literatura Latinoamericana y del Caribe en Ciencias de la Salud (LILACS). Se han detectado 30 artículos que se utilizan en los artículos. Resultados: después de la lectura y análisis de los artículos, surgieron las siguientes categorías temáticas: Medidas de prevención a la violencia obstétrica; Experiencias con la prevención de la violencia obstétrica y Conociendo los factores de riesgo para la violencia obstétrica. El enfermero buscar en su asistencia el vínculo con la parturienta para proporcionar un parto saludable, evitando así la violencia obstétrica. Conclusión: Para prevenir la violencia obstétrica se hace necesaria una asistencia de enfermería y un ambiente que proporcionen la autonomía de la mujer gestante.Descriptores: Violência; Embarazo; Asistencia de Enfermería.
This paper describes an approach introducing location intelligence using open-source software components as the solution for planning and construction of the airport infrastructure. As a case study, the spatial information system of the International Airport in Sarajevo is selected. Due to the frequent construction work on new terminals and the increase of existing airport capacities, as one of the measures for more efficient management of airport infrastructures, the development team has suggested to airport management to introduce location intelligence, meaning to upgrade the existing information system with a functional WebGIS solution. This solution is based on OpenGeo architecture that includes a set of spatial data management technologies used to create an online internet map and build a location intelligence infrastructure.
This article discusses the application of thermoelectric (TE) materials in building facade systems, which can be used to create active exterior enclosures. TEs are semiconductors that have the ability to produce a temperature gradient when electricity is applied, exploiting the Peltier effect, or to generate a voltage when exposed to a temperature gradient, utilizing the Seebeck effect. TEs can be used for heating, cooling, or electricity generation. In this research, heating and cooling applications of these novel systems were explored. We designed and constructed two prototypes, where one prototype was used to study integration of TE modules (TEMs) as stand-alone elements in the facade, and one prototype was used to explore integration of TEMs and heat sinks in facade assemblies. Both prototypes were tested for heating and cooling potential, using a thermal chamber to represent four different exterior environmental conditions (-18°C, -1°C, 16°C and 32°C). The interior ambient conditions were kept constant at room temperature. The supplied voltage to facade-integrated TEMs varied from 1 to 8 V. We measured temperature outputs of TEMs for all investigated thermal conditions using thermal imaging, which are discussed in this article. The results indicate that while stand-alone facade-integrated TEMs are not stable, addition of heat sinks improves their performance drastically. Facade-integrated TEMs with heatsinks showed that they would operate well in heating and cooling modes under varying exterior environmental conditions.
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