Water hardness and deposition of incrustation is a problem in households and industry. In this regard, several technologies have been developed with the purpose of water softening and preventing the deposition of incrustation. The ion exchange method is the most commonly used method and is considered a conventional method. However, due to the shortcomings of this method, there is a need to develop adequate alternative methods. The potential of the method using biosorbents such as moss Leucobryum glaucum and Spaghnum peat moss for the purpose of removing water hardness has recently become the subject of intensive research with growing interest. In this study, the method using Leucobryum glaucum as a biosorbent was tested and a comparison was made with the conventional method and previously conducted studies that used other biosorbents.
In this research, the results of bentonite characterization (pH value of bentonite suspension, point of zero charge, cation exchange capacity, SEM, XRF, DTG) are presented. The results of lead (II) removal efficiency at initial lead (II) concentrations of 200, 300 and 400 mg/L, and biosorbent dosage of 1 gram in 50 ml of lead(II) solution, are also presented, as well as the values of the Freundlich and Langmuir constants from the Freundlich and Langmuir adsorption isotherms. The obtained results showed that removal efficiency is high for all three examined initial lead (II) concentrations, and it is above 99%. The lead (II) removal efficiency slightly decreases with an increase in initial lead concentration. Experimental data obtained from adsorption experiment with contact time of 2.5 minutes, stirring rate 100 rpm, temperature 250C and pH value 5 are better fitted with the linearized Langmuir equation isotherm, giving an R2 value closest to unity (0.9994), than to linearized Freundlich equation (0.9886).
Water sources have become unsafe for human consumption, but also for use in agriculture for irrigation or for the food industry. The deteriorating water quality has led to a shortage of drinking water supply. The aim of this study was to examine the possibility of using agricultural waste, specifically corn residues, (corn cob and silk) as a bioadsorbent to remove Ni and Cd ions from water. Experimental results have shown that corn residues (corn cob and corn silk) have a certain potential for use as bioadsorbents. The possibility of application was tested for corn cob and corn silk (corn cob 3.5g and corn silk 1.5g) for metal concentrations of 20, 40, 100 mg/L for corn cob, and 40 mg/L and 100 mg/L for corn silk. The tests were performed at pH 3 and 6 at a contact time to reach equilibrium of 3.5 hours. Adsorption parameters were determined using the Freundlich isotherm. The morphology of biosorbents before and after the adsorption process was monitored to observe differences in the structure of the biosorbents used. The results showed that in the case of Cd2 + ions, with an initial concentration of 100 mg/L the highest removal efficiency was achieved for all samples used, while in the case of Ni2+ ions the highest removal efficiency was achieved at an initial concentration of 40 mg/L for all samples, while the corn silk based of the maize (Zea mays L.) sample proved to be the best for the removal of these ions where the influence of pH has a great influence on the removal efficiency as well as the physico-chemical properties of the metal. Morphological analysis of samples before and after the adsorption process showed significant differences in the structure of the biosorbents used, which lead to the conclusion that sorption is associated with chemical changes on the surface of the biosorbent. The calculated values of the parameters used in the Freundlich isotherm indicated the existence of high-energy sorption centers in the bisorbent of corn cob and corn silk hybrids maize, and that the adsorption was more pronounced at lower pH values. The corn cob-based of the maize (Zea mays L.) biosorbent used has been shown to be a heterogeneous surface biosorbent with moderate sorption intensity to Ni and Cd ions, and good sorption intensity to Ni and Cd ions in corn silk-based biosorbent.
The natural plant Cornus mas, sometimes called Cornelian cherry, has been known since ancient times and the fruit is used for various purposes. Cornus mas gives healthy fruits without the use of chemical protection, which are used as healthy, tasty and medicinal food. Cornus mas fruits can be used for eating fresh or in the form of numerous processed products: marmalade, jam, sweet, compote, syrup, juice, fruit yogurt, liqueur, wine and brandy. Due to its antioxidant, antiallergic, antimicrobial and antihistamine properties, it is increasingly used as a dietary supplement, as well as for medical purposes. Taking into account all the above, the aim of this paper is to examine samples of a mixture of honey and fresh wild Cornelian cherry, as well as a sample of honey and Cornelian cherry and determine the physical - chemical parameters: electrical conductivity, pH value, vitamin C content, HMF (hydroxy methyl furfural), as well as individual heavy metals such as iron, cadmium, lead, zinc, copper. Based on the obtained results, appropriate conclusions will be given and the possibility of registering these products as food supplements will be determined. Based on the performed analyzes, it was shown that the sample of honey and Cornelian cherry mixture had the highest pH value and electrical conductivity, and that the honey sample had the lowest value. Also, the highest value of water activity had the sample of a mixture of honey and Cornelian cherry, while the highest content of hydroxymethylfurfural had the content of Cornelian cherry. The analysis showed the absence of manganese (Mn), cadmium (Cd) and lead (Pb) in all samples, while it was shown that the highest content of Cu and Zn has the sample of Cornelian cherry 2.665 mg/kg Cu and 14.41 mg/kg Zn, followed by a mixture of Cornelian cherry and honey Cu 2.778 mg/kg, Zn 14.670 mg/kg, while the honey sample has the highest Fe content of 16.72 mg/kg. This shows that the samples are rich in zinc, iron and copper, and that they are a good source for those minerals that could meet daily needs.
During the last few years, we have witnessed more frequent floods affecting the northeastern part of Bosnia and Herzegovina, the valley of the Spreca River. Flooded soil has undergone various changes, in terms of numerous deficiencies and heavy metal contamination, where such soil represents a great danger both for people and animals. Therefore, in this paper the physicochemical analysis of soil and degree of pollution is determined. The aim of soil sampling and analysis is to determine its status after water withdrawal, in terms of nutrient supply, and to determine possible chemical pollution. Based on the results obtained, agricultural producers will receive recommendations regarding restoration of production on these areas, the choice of cultivated culture, corrective measures or remediation of these areas. As part of the analysis, hygroscopic moisture, acid-base soil status, oxidoreduction potential, organic matter content, carbonate content and heavy metals content were determined. Based on the performed analyzes, the soil was shown to be of neutral character (determined in 1M KCl), and weakly alkaline (determined in distilled H2O) with predominantly reducing condition prevailing in the soil. The conducted analyzes have shown that the soil is very poor in humus, and that the heavy metals content is within the limit values determined by the Rulebook on Determination of Allowed Quantities of Harmful and Dangerous Substances in Soil and Method of Testing there of (“Official Gazette of Federation of Bosnia and Herzegovina”, number 52/09). Therefore, from the aspect of the pollution degree, the soil from this plot belongs to the first class when it comes to iron, manganese, cadmium and lead, to the second class when it comes to zinc, and the third class when it comes to copper.
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