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Mirnesa Zohorović

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Water hardness and deposition of incrustation is a problem in households and industry. In this regard, several technologies have been developed with the purpose of water softening and preventing the deposition of incrustation. The ion exchange method is the most commonly used method and is considered a conventional method. However, due to the shortcomings of this method, there is a need to develop adequate alternative methods. The potential of the method using biosorbents such as moss Leucobryum glaucum and Spaghnum peat moss for the purpose of removing water hardness has recently become the subject of intensive research with growing interest. In this study, the method using Leucobryum glaucum as a biosorbent was tested and a comparison was made with the conventional method and previously conducted studies that used other biosorbents.

Pelotherapy is the application of thermal muds (peloids) for therapeutic purposes. Artificial peloids were prepared usingpyrophilite shale maturated in three different types of thermal water in terms of their pH values. The samples after 30and 60 days of maturation were examined by X-ray diffraction. No significant variations in the mineralogical compositionand diffractograms of pyrophillite peloids were detected after maturation. Only the influence of the maturation processof pyrophillite on the pH value of mineral water with high and low pH value is noticed.

Sludge generated in wastewater treatment processes must be treated in an adequate manner, and therefore disposed of in an environmentally friendly manner. The biggest obstacle to the efficient use of sludge is the high water content, therefore the development of methods to accelerate the sludge dewatering process is particularly important. For the purposes of the research, the waste sludge created in the process of purifying ammoniaphenol wastewater in the GIKIL factory was used. Sludge conditioning was performed by adding a commercial flocculant (0.1 % solution) in combination with pyrophyllite, kaolin clay and shredded cardboard. According to earlier research, the volume of waste sludge with the addition of a suitable flocculant could be reduced by more than 5 times compared to the initial amount, leaving behind a large amount of separated water that can be returned to the process. The results show that the addition of commercial flocculant in the amount of 0.8 % gives the best results (reduction of sludge volume by 78.8 %). A lower percentage was found in samples with a mixture of flocculants with pyrophyllite (78 %) and kaolin (77.6 %), while the combination of flocculants with waste cardboard was ineffective (64.4 %). Addition of flocculant to waste sludge resulted in a decrease in specific filtration resistance (1.15x107 s2/g). A decrease in specific resistance was also observed in flocculant/kaolin clay (0.8x107 s2/g) and flocculant/cardboard (1.09x107 s2/g) samples. Sludge conditioning also resulted in a reduction of suspended solids in the neonate compared to settled raw sludge without additives.

Using natural and modified Ca-bentonite as an adsorbent to observe a satisfactory trend in the removal of heavy metal ions As(V) and Hg(II) from simulated wastewaters. In this original scientific paper, Ca-bentonite was modified in two ways, thermally activated at a temperature of 300 °C for 3 hours and acid activated with HCl and H2SO4, molar concentrations 0,4 mol/L. Ca-bentonite used in this original scientific work was used from the Shipovo mine (Šipovo mine), Bosnia and Herzegovina and proved to be an excellent bioadsorbent for the removal of present ions from simulated wastewaters. Also this is eco-friendly adsorbent and low costed compared to other expensive adsorbents. Due to its chemical composition in which two oxides predominate, namely SiO2 (48.28 mass %) and Al2O3 (23.04 mass%), it can be concluded that Ca-bentonite from the Shipovo mine (Šipovo mine), Bosnia and Herzegovina belongs to the group of refractory materials. The highest removal efficiency of As(V) ions expressed in % was 75.11 at the initial concentration of 1.5 mg/L and was recorded using HCl acid-activated Ca-bentonite. The efficiency of Hg(II) ion removal was the highest using thermally activated Ca-bentonite and this value was 99.66% at an initial concentration of 1 mg/L.

Although it is primarily grown as food, corn also represents a very good raw material for the production of biogas due to the favourable starch and fibre ratio that is the basis of its structure. In addition, an important fact is that there are large arable or potentially arable areas in our country that are triturated with different pollutants, so that the production of plant crops for dietary purposes on these surfaces is not possible. The aim of this paper was to determine the biometric potential of various varieties of corn grain in laboratory conditions through a series of experimental measurements. The obtained results are based on the assessment of the possibility of applying energy plantations of corn grown on contaminated arable or recultivated surfaces in the production of biogas.

M. Zohorović, F. Andrejaš, V. Stuhli, Samra, Halilovic, M. Selimbašić

The proper process control is the key to achieving both environmental and commercial goals of conducting the process of anaerobic digestion. Taking into account that the parameters that can be monitored are quite numerous, and that the monitoring equipment, its installation and maintenance require significant financial resources, it is, from commercial aspect, necessary to minimize the number of parameters to the set of parameters which are necessary but sufficient for the proper conduct of the process to the point after which the further continuation of the process is not economically justified. The paper presents the model developed for determination of the minimum number of parameters to be monitored in order to ensure sufficient quality control of this process and describes its validation through the laboratory test.

Due to the increased use of fossil fuels and industrial production, the concentration of carbon dioxide in the atmosphere increases, causing greenhouse effect and, consequently, climate change. Stationary CO2 sources like coal power plants produce the bulk of the world’s CO2 emissions. Electricity and heat plants and other fuel transformation activities account for 40% of total global CO2 emissions. Therefore, great interest in the possibilities of CCS systems to reduce CO2 emission is evident, either through removal or reduction measures. The experimental part of this paper deals with the determination of the potential of alternative media for use in CCS technologies, describing the lab-scale investigation. The role of alternative media in that context has been assigned to recurrent water from fly ash and slag disposal pond Jezero II of Power Plant Tuzla. When choosing an alternative medium for CCS applications, the following features were considered: that the medium currently has a negative impact on the environment; that the medium is available in sufficient quantities; that the medium has a low price and that its final disposal causes costs. Hence, the ability of the selected media (recurrent water) for CO2 capture has been confirmed and its capacity in that context roughly determined.

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