The natural plant Cornus mas, sometimes called Cornelian cherry, has been known since ancient times and the fruit is used for various purposes. Cornus mas gives healthy fruits without the use of chemical protection, which are used as healthy, tasty and medicinal food. Cornus mas fruits can be used for eating fresh or in the form of numerous processed products: marmalade, jam, sweet, compote, syrup, juice, fruit yogurt, liqueur, wine and brandy. Due to its antioxidant, antiallergic, antimicrobial and antihistamine properties, it is increasingly used as a dietary supplement, as well as for medical purposes. Taking into account all the above, the aim of this paper is to examine samples of a mixture of honey and fresh wild Cornelian cherry, as well as a sample of honey and Cornelian cherry and determine the physical - chemical parameters: electrical conductivity, pH value, vitamin C content, HMF (hydroxy methyl furfural), as well as individual heavy metals such as iron, cadmium, lead, zinc, copper. Based on the obtained results, appropriate conclusions will be given and the possibility of registering these products as food supplements will be determined. Based on the performed analyzes, it was shown that the sample of honey and Cornelian cherry mixture had the highest pH value and electrical conductivity, and that the honey sample had the lowest value. Also, the highest value of water activity had the sample of a mixture of honey and Cornelian cherry, while the highest content of hydroxymethylfurfural had the content of Cornelian cherry. The analysis showed the absence of manganese (Mn), cadmium (Cd) and lead (Pb) in all samples, while it was shown that the highest content of Cu and Zn has the sample of Cornelian cherry 2.665 mg/kg Cu and 14.41 mg/kg Zn, followed by a mixture of Cornelian cherry and honey Cu 2.778 mg/kg, Zn 14.670 mg/kg, while the honey sample has the highest Fe content of 16.72 mg/kg. This shows that the samples are rich in zinc, iron and copper, and that they are a good source for those minerals that could meet daily needs.
During the last few years, we have witnessed more frequent floods affecting the northeastern part of Bosnia and Herzegovina, the valley of the Spreca River. Flooded soil has undergone various changes, in terms of numerous deficiencies and heavy metal contamination, where such soil represents a great danger both for people and animals. Therefore, in this paper the physicochemical analysis of soil and degree of pollution is determined. The aim of soil sampling and analysis is to determine its status after water withdrawal, in terms of nutrient supply, and to determine possible chemical pollution. Based on the results obtained, agricultural producers will receive recommendations regarding restoration of production on these areas, the choice of cultivated culture, corrective measures or remediation of these areas. As part of the analysis, hygroscopic moisture, acid-base soil status, oxidoreduction potential, organic matter content, carbonate content and heavy metals content were determined. Based on the performed analyzes, the soil was shown to be of neutral character (determined in 1M KCl), and weakly alkaline (determined in distilled H2O) with predominantly reducing condition prevailing in the soil. The conducted analyzes have shown that the soil is very poor in humus, and that the heavy metals content is within the limit values determined by the Rulebook on Determination of Allowed Quantities of Harmful and Dangerous Substances in Soil and Method of Testing there of (“Official Gazette of Federation of Bosnia and Herzegovina”, number 52/09). Therefore, from the aspect of the pollution degree, the soil from this plot belongs to the first class when it comes to iron, manganese, cadmium and lead, to the second class when it comes to zinc, and the third class when it comes to copper.
During the last few years, we have witnessed more frequent floods affecting the northeastern part of Bosnia and Herzegovina, the valley of the Spreca River. Flooded soil has undergone various changes, in terms of numerous deficiencies and heavy metal contamination, where such soil represents a great danger both for people and animals. Therefore, in this paper the physicochemical analysis of soil and degree of pollution is determined. The aim of soil sampling and analysis is to determine its status after water withdrawal, in terms of nutrient supply, and to determine possible chemical pollution. Based on the results obtained, agricultural producers will receive recommendations regarding restoration of production on these areas, the choice of cultivated culture, corrective measures or remediation of these areas. As part of the analysis, hygroscopic moisture, acid-base soil status, oxidoreduction potential, organic matter content, carbonate content and heavy metals content were determined. Based on the performed analyzes, the soil was shown to be of neutral character (determined in 1M KCl), and weakly alkaline (determined in distilled H2O) with predominantly reducing condition prevailing in the soil. The conducted analyzes have shown that the soil is very poor in humus, and that the heavy metals content is within the limit values determined by the Rulebook on Determination of Allowed Quantities of Harmful and Dangerous Substances in Soil and Method of Testing there of (“Official Gazette of Federation of Bosnia and Herzegovina”, number 52/09). Therefore, from the aspect of the pollution degree, the soil from this plot belongs to the first class when it comes to iron, manganese, cadmium and lead, to the second class when it comes to zinc, and the third class when it comes to copper.
The effect of pH and initial concentration on the removal of Cu(II) and Ni(II) ions from their monocomponent and two-component aqueous solutions using Na2CO3 as a chemical precipitation agent was investigated in this paper. Monocomponent aqueous solutions of Cu(II) and Ni(II) ions with their initial concentrations of 50 and 500 mg/L and two-component aqueous solution with initial concentration of 500 mg/L were prepared. The precipitation was carried out by batch method at room temperature by stirring the solution at 300 rpm for 5 minutes, resulting in the formation of precipitates. The resulting precipitate was separated by filtration from the solution. The experiment proved that Na2CO3 is a good agent for removing Cu(II) and Ni(II) ions from their monocomponent water solutions of 50 and 500 mg/L concentration and two-component water solution with initial concentration of each metal 500 mg/L. The percentage of Cu(II) removal was higher at lower pH values compared to Ni(II) removal.
Wastewaters from the galvanization process contain high concentrations of heavy metals representing a great danger to human health as well as to the environment. Heavy metals in the galvanization process are used in the coating process, whereby the coatings of certain metals are formed. The treatment of wastewaters generated by the galvanization process can be conducted by a number of methods, however, today more research is being done on processes which are efficient, economical and cost-effective, but environmentally acceptable. One of those techniques is adsorption. The adsorption process of Cd2+, Ni2+ and Cr2+ions from galvanization water using brewer’s grain as the adsorbent, at different pH values and adsorbent granulation of 0.5 mm is analyzed in this paper. The percentage of moisture and ash was determined, and the FTIR analysis was performed confirming the presence of certain functional groups. Based on the obtained values, it has been shown that the brewer’s grain can be successfully used as a natural adsorbent to remove Cd2+, Ni2+ and Cr2+ ions from galvanization waters, and also that high level of efficiency is obtained at all analyzed pH values. The analysis has also shown that the affinity of adsorbents to Cd2+, Ni2+ and Cr2+ ions is in correlation with physical and chemical properties, but that the best removal efficiency is achieved at the pH 4 value
The problem of environmental pollution is more expressed and more present by the development of the industry and the growth of the human population. Pollution of natural and wastewater is most often due to the release of heavy metals into watercourses. The greatest challenge for researchers is choosing the right biomass from a large number of low-cost biomaterials, and availability and price are very important selection factors. Microbial biomass, forestry waste and agroindustrial complexes are most frequently examined, as well as various macromolecules of natural origin. In this paper, barley straw that arises as agricultural waste product in barley production in Bosnia and Herzegovina, was used as a biosorbent. In the experimental part, physical and chemical characterization of barley straw was performed, after which the efficiency of removing Cd(II) and Ni(II) from aqueous solutions, using barley straw, and the influence of process parameters (pH value of aqueous solution, biosorbent size, interaction of metal ions) on the biosorption capacity were tested. It can be concluded that barley straw has good adsoption characteristics for the use as a low-cost natural sorbent for the removal of heavy metals from water.
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