Nigella sativa is a herb that has been used for centuries to treat various ailments, including infectious diseases. The aim of this work was to show in laboratory conditions the influence of different temperature regimes and methods of storage of Nigella Sativa oils on their physicochemical properties and microbiological stability. Analyzes have established that the temperature and method of storage have a significant influence on the change in the quality of the oil, especially when it comes to the total acidity of the oil and the peroxide value, where the values increased with the time of storage. The lowest obtained value for the peroxide number was at the first measurement, Pb = 9.99, which meets the prescribed standards for safe use, then the highest obtained value was 34.47 for the sample that was constantly exposed to the sun in a bright bottle. Also, the values of the iodine number increased with time, where the lowest value obtained was 14.56, and the highest was 102.48. Therefore, it is extremely important that the oil is stored in suitable packaging in dark glass bottles, and that it is protected from direct sunlight and high temperatures.

Physical chemical milk is an emulsion of milk fat in an aqueous solution of proteins, milk sugar and mineral salts. The high molar conductivity of goat milk samples compared to cow's milk indicates a high content of mineral substances. That goat milk is rich in total proteins is also indicated by the protein content in the samples, which are higher than the cow's milk samples. However, higher fat content was recorded in cow's milk samples, which also results in higher surface tension of cow's milk. The freezing point and refractive index of goat milk are higher compared to literature data and cow milk samples. The acidity of goat's milk comes from the acidic properties of casein, citrate, phosphate, etc. it is lower than cow's milk and is in accordance with literature data. The viscosity of pasteurized goat's milk at all temperatures is also higher than that of cow's milk.

In accordance with consumer requirements, the water must be adequately purified, and the corresponding parameters within the defined values. Various methods are used for this purpose, of which the ion exchange method can be highlighted as the simplest, most efficient and economically profitable. Ion exchange is a reversible process of ion exchange between a solid phase and an electrolyte solution. The ion exchanger is a macromolecular insoluble material that has chemically bound electrified groups and mobile, oppositely charged ions that compensate for this electrification. Ion exchangers are usually used in the form of compact or granular beds that fill the column through which the solution with the ions to be exchanged flows.They usually contain phenolic, carboxylic, sulfonic amino and other groups, which is why the treatment also results in decarbonization, softening, demineralization and denitrification of water. As the assessment of water quality is based on the most significant physico-chemical parameters, the aim of the work is the analysis of drinking water before and after treatment with an ion exchanger.For this purpose, organoleptic parameters such as smell, taste and color were first analyzed. After that, physico-chemical parameters were analyzed: pH values, electrical conductivity, m-alkalinity, p-alkalinity, water hardness, organic matter content, chloride content, iron and manganese content. An ion exchanger based on resin was used, which after use was regenerated by washing with NaClsolution.The analysis of the water sample, before and after the ion exchange treatment, showed that the treatment process was effective and that the decarbonization and softening of the water was carried out, whereby the water was categorized as soft water (water <9⁰dH).The analyzed water is tasteless, odorless and colorless before and after treatment. The results of the analysis showed that all the values of the analyzedphysico-chemical parametersare in accordance with the Rulebook on the Healthiness of Drinking Water(Official Gazetteof Federation of Bosnia and Herzegovina No.40/10) arebelow the maximum allowed values. KEYWORDS:water, ion exchange, physical-chemical parameters; water treatment

Waste water in the galvanic process contains high concentrations of heavy metals that pose a direct danger to humans and the environment. Conventional methods for their removal are quite expensive and generate a large amount of waste. The development of new and improvement of existing methods for the removal of heavy metals from galvanic wastewater are the subject of many studies. Compared to other purification methods, the adsorption is becoming an increasingly popular method of wastewater purification, especially if the adsorbent is cheap, easily available and does not require any other treatment before use. Therefore, the aim of the work was to investigate the possibility of using natural bentonite for the removal of heavy metal ions from multi-component water systems of the galvanic industry. For this purpose, the physico-chemical characterization of natural bentonite was performed, and then the influence of pH value, time and temperature on the adsorption efficiency was examined. The results of adsorption showed that natural bentonite can be used as an adsorbent for the removal of heavy metal ions from waste galvanic waters, and that at pH 5 it achieves the maximum removal efficiency for Cu(II):Cr(III):Ni(II) ions in the percentage ratio 100 : 99.990 : 99.998. The results showed that the highest removal efficiency for Cu (II) ions was achieved in the first 10 minutes, and 20 minutes for Cr (III) and Ni (II) ions. The maximum efficiency of Cu (II) removal was achieved at all temperatures, while for Cr (III) 99.99% and Ni (II) 100% maximum efficiency was achieved at 35°C, which indicates that the adsorption process is endothermic. The experimental results of the adsorption of Cu (II) metal ions are in good agreement with the Langmuir and Freundlich theoretical models, while for Cr (III) and Ni (II) ions they are in better agreement with the Langmuir adsorption model.

Medicinal plants have become an increasing subject of interest worldwide due to the large amount of biologically active substances that have potential beneficial health properties. One of the more interesting popular medicinal plants is hawthorn (Crataegusspp.), a deciduous branched shrub that is increasingly used for health purposes. Various parts of this plant, including berries, flowers and leaves, are rich in nutrients and beneficial bioactive compounds that are effective in the treatment of numerous diseases. Honey is a natural sweetener produced by bees from plant secretions. Known for its nutritional and medicinal values, it gives strength to the body, which is why it is indispensable in the human diet. The combination of these two ingredients represents a significant source of vitamins and minerals in daily use, but also for use in various pharmaceutical and medical purpose. Taking into account all of the above, the aim of the work is to test samples of the mixture of honey and hawthorn in different proportions and determine the physical and chemical characteristics: pH value, electrical conductivity, refractive index, viscosity, water activity, HMF, DPPH. Based on the analysis, appropriate conclusions will be drawn and more information will be obtained about their quality and possible use as a food supplement. On the basis of the conducted analyses, it can be concluded that the parameter values are within the permitted limits defined by the Rulebook (Official Gazette Bosnia and Herzegovina No. 37/09). The analysis of the mentioned parameters showed that the chemical composition of the sample plays a major role in the value of the measurement results, and that Sample III has the best antioxidant properties. KEYWORDS:physicochemical characteristics; honey; hawthorn (Crataegus spp.);mixture; food suplement

Providing the population with sufficient quantities of hygienically healthy food is the foundation of public health protection. According to the current BiH Law on Food, the main goal is to ensure a high level of human health protection, and the measures applied should be based on risk assessment. Regular food monitoring is one of the key public health problems, and this paper presents the quantitative risk of copper intake by consuming mint herbal tea infusions. The average copper concentration in the 20 analyzed samples of mint herbal tea infusions was 0.0028 ± 0.0125 mg / kg, while the value of the average daily intake was less than the oral reference dose for copper, so that the hazard coefficient itself was <1 , and consuming the analyzed infusions of herbal mint tea has no harmful effects on the health of the surveyed children.

pH represents the concentration of free H+ in pine needles extracts (PNE) and is therefore an important initial parameter in quality control. Electrical conductivity and pH of samples of fresh and stored for 20 days of PNE with black cumin oil and olive oil had values of 0.00 due to the encapsulation of water molecules, pH and electrical conduction was not possible. The pH of the other samples was in a weakly acidic environment because the pH of natural pine needles is 3.8. Electrical conductivity values in all samples except pine needle extract and honey increased during storage. By monitoring the parameters of pH and electrical conductivity in the quality control of PNE, it gives us a significant insight into the physical state of the phases and the way of storage.

There are data in the literature on the influence of higher amounts of organic selenium on production results, and the obtained results indicate that high levels of organic selenium added to feed (even up to 15 mg / kg) of chickens did not have a negative effect on production results. Also, in the literature related to chicken nutrition there is data on the use of different forms (inorganic, organic) and different amounts of selenium on carcass meat, pH value of meat, ability to bind water, chemical parameters of meat quality, oxidative stability of meat, and and on the sensory properties of broiler meat. Of particular importance are the studies of the possibility of using increased amounts of organic selenium in poultry nutrition in order to enrich meat with selenium. This is of particular importance for the nutritional value of meat, and in connection with this, human health. The aim of this study was to investigate the effect of adding different amounts of organic selenium (ALKOSEL® R397) in concentrate mixtures on the sensory properties of meat streams.

One of the most important public- health tasks is to provide hygienic and healthy food and water, which will not have harmful consequences for the health of consumers, and in this way a safe food trade is ensured, therefore protecting everyone in the chain from the producer to the consumer. This paper presents the concentrations of heavy metals Fe, Mn, Zn and Cu, obtained by atomic absorption spectrophotometry (AAS), from 5 samples of thyme infusion (lat. Thymus serpyllum), which can be found on the market of Travnik. Sample infusions were prepared by holding the filter bags in boiling deionized water for 10 minutes. Mean values of concentrations of these heavy metals were for Fe 0.0508 ± 0.0139 mg/kg, Mn 0.06 ± 0.0069 mg/kg, Zn 0.0436 ± 0.0147 mg/kg, while the Cu content was not detected in any infusion of the said tea. The risk assessment of the intake of tested heavy metals for the health of consumers, expressed through the Hazard Index (HI), which was <1, shows that the samples of analyzed teas are safe for consumption.

From ancient times the natural plant Cornelian cherry is used for various purposes. The healing properties of Cornelian cherry suit the human body and give it the necessary vitamins, acids, and everything else it needs for the body to function normally and healthily. Due to its antioxidant, antiallergic, antimicrobial, and antihistamine properties, it is increasingly used as a dietary supplement, as well as for medical and pharmaceutical purposes. In addition to the fruit of the Cornelian cherry, in the past, the oil of Cornelian cherry seeds was used, the content of which can be up to 30%. However, the data available in the literature are scanty and do not show true values because the oil content depends on many factors, such as the geographical origin of the Cornelian cherry, the harvest period, varieties, etc., which also affects the oil content in the seeds. Therefore, the aim of this study is to determine the average oil content of Cornelian cherry seeds, and to determine the obtained oil physico-chemical parameters that show the quality of the oil, namely oil viscosity, iodine value, peroxide value, acid value, and saponification value. Based on the obtained results, more information is clearly given about the quality of the obtained oil, as well as its use in the production of cosmetic preparations. Based on the conducted analyzes, it was shown that the oil obtained from the Cornelian cherry seeds was high quality, and that it was analyzed in its fatty acid composition similar to other vegetable oils such as sunflower oil, pumpkin oil, corn oil. The low of the peroxide value showed that the oil used has good resistance to oxidative spoilage, which is attributed to the composition of fatty acids and the presence of oil components that have a pronounced antioxidant effect, while the iodine value indicates that it is oil rich in saturated fatty acids such as palmitic, stearic and arachid, etc. where genotype plays an important role. The saponification value showed that these are fatty acids present in the triacylglycerols of this oil, which are low molecular weight, ie there are fewer of those with a larger number of C atoms. All obtained values ​​of the analyzed physical and chemical parameters are in accordance with the requirements imposed by the Regulations on edible vegetable oils (Official Gazette of the Federation Bosnia and Herzegovina No.21/11.), and as such can be used for cosmetic purposes.

The industrialization of agriculture has led to the great use of pesticides, which leads to huge global problems, such as the production of safe food that is safe for humans and the environment. By heavy metals we mean elements whose relative density is above 5 g cm-3, heavy metals can be divided into essential trace elements (Fe, Cu, Zn, Mo, Mn, Ni) and toxic elements (Pb, Cd, Cr, As, Hg ). Heavy metals are represented 25% in the soil, and the largest percentage is occupied by K, Fe, Mg, Ca, Al, Na. In addition to anthropogenic processes such as urbanization, traffic, industrialization, heavy metals can be a consequence of natural or pedogenetic processes, ie. inheritance from the parent substrate. The aim of this study was to determine the content of heavy metals Lead and Cadmium in the examined samples, to compare the obtained samples with the norms of the EU and BiH and the influence of the content of heavy metals on the quality of honey. Data collection was performed on the basis of honey analysis of four producers from the area of ​​Tuzla, Lukavac, Živinice and Bihac. The analysis was performed on February 18, 2020. to 25.02.2020. years. The analysis of the processed data was performed in the statistical program IBM SPSS.

One of the most important agricultural activities is certainly beekeeping, which significantly contributes to the preservation of biodiversity and the improvement of agricultural and, above all, fruit production. In its approach to the European Union, Bosnia and Herzegovina follows the trends and harmonizes its legal legislation in many segments that relate to agriculture and beekeeping as its very important segment. According to the available land per capita, Bosnia and Herzegovina does not lag behind European countries, because it has a great potential for agricultural production that has not been used. The application of legal norms in beekeeping production is the basis for success in production, as well as health and food quality. The primary goal of this study was to determine the influence of physicochemical properties on honey quality. Data collection was performed on the basis of honey analysis of four producers from the area of ​​Tuzla, Lukavac, Živinice and Bihac. The analysis was performed on February 18, 2020. to 25.02.2020. years. The analysis of samples and their physico-chemical parameters proved that there are statistically significant differences between the examined types of honey. The analysis of the main components was performed with the aim of detecting the difference in quality. The analysis of the processed data was performed in the statistical program IBM SPSS.

The aim of this study was to investigate the effect of the addition of different amounts of organic selenium (ALKOSEL® R397) in concentrate mixtures on the selenium content in the blood plasma and feces of ducks. The experiment was performed on 240 one-day-old ducklings (Cherry Valley) which were freely selected into 4 groups, one control K0 group, and three experimental K1, K2 and K3 groups. In two phases of feeding in fattening, ducklings were fed with two and nutritionally different concentrate feed mixtures: starter (from 1 to 14 days) and finisher (from 15 to 49 days of fattening). The control group of ducklings (K0) during feeding received food without added organic selenium in both phases of fattening. In both phases of fattening, the experimental group of ducks K1 was fed with food as well as the control group, but with the addition of 0.2 mg/kg of organic selenium, while the experimental group K2 used food with 0.4 mg/kg, and the experimental group K3 with 0.6 mg/kg of organic selenium. The addition of organic selenium to duck feed had the effect of increasing selenium content in both blood plasma and duck feces. The highest content of selenium in blood plasma and feces was determined in the group of ducks that received the highest amount of organic selenium through food during the entire experiment.

The natural plant Cornus mas, sometimes called Cornelian cherry, has been known since ancient times and the fruit is used for various purposes. Cornus mas gives healthy fruits without the use of chemical protection, which are used as healthy, tasty and medicinal food. Cornus mas fruits can be used for eating fresh or in the form of numerous processed products: marmalade, jam, sweet, compote, syrup, juice, fruit yogurt, liqueur, wine and brandy. Due to its antioxidant, antiallergic, antimicrobial and antihistamine properties, it is increasingly used as a dietary supplement, as well as for medical purposes. Taking into account all the above, the aim of this paper is to examine samples of a mixture of honey and fresh wild Cornelian cherry, as well as a sample of honey and Cornelian cherry and determine the physical - chemical parameters: electrical conductivity, pH value, vitamin C content, HMF (hydroxy methyl furfural), as well as individual heavy metals such as iron, cadmium, lead, zinc, copper. Based on the obtained results, appropriate conclusions will be given and the possibility of registering these products as food supplements will be determined.  Based on the performed analyzes, it was shown that the sample of honey and Cornelian cherry mixture had the highest pH value and electrical conductivity, and that the honey sample had the lowest value. Also, the highest value of water activity had the sample of a mixture of honey and Cornelian cherry, while the highest content of hydroxymethylfurfural had the content of Cornelian cherry. The analysis showed the absence of manganese (Mn), cadmium (Cd) and lead (Pb) in all samples, while it was shown that the highest content of Cu and Zn has the sample of Cornelian cherry 2.665 mg/kg Cu ​​and 14.41 mg/kg Zn, followed by a mixture of Cornelian cherry and honey Cu 2.778 mg/kg, Zn 14.670 mg/kg, while the honey sample has the highest Fe content of 16.72 mg/kg. This shows that the samples are rich in zinc, iron and copper, and that they are a good source for those minerals that could meet daily needs.

During the last few years, we have witnessed more frequent floods affecting the northeastern part of Bosnia and Herzegovina, the valley of the Spreca River. Flooded soil has undergone various changes, in terms of numerous deficiencies and heavy metal contamination, where such soil represents a great danger both for people and animals. Therefore, in this paper the physicochemical analysis of soil and degree of pollution is determined. The aim of soil sampling and analysis is to determine its status after water withdrawal, in terms of nutrient supply, and to determine possible chemical pollution. Based on the results obtained, agricultural producers will receive recommendations regarding restoration of production on these areas, the choice of cultivated culture, corrective measures or remediation of these areas. As part of the analysis, hygroscopic moisture, acid-base soil status, oxidoreduction potential, organic matter content, carbonate content and heavy metals content were determined. Based on the performed analyzes, the soil was shown to be of neutral character (determined in 1M KCl), and weakly alkaline (determined in distilled H2O) with predominantly reducing condition prevailing in the soil. The conducted analyzes have shown that the soil is very poor in humus, and that the heavy metals content is within the limit values determined by the Rulebook on Determination of Allowed Quantities of Harmful and Dangerous Substances in Soil and Method of Testing there of (“Official Gazette of Federation of Bosnia and Herzegovina”, number 52/09). Therefore, from the aspect of the pollution degree, the soil from this plot belongs to the first class when it comes to iron, manganese, cadmium and lead, to the second class when it comes to zinc, and the third class when it comes to copper.