Introduction: The main purpose of root canal filling materials is to provide an apical sealing that prevents the movement of bacteria and the diffusion of their metabolic products from the root canal system to periapical tissue. The aim of this study was to evaluate the apical sealing ability of mineral trioxide aggregate’s (MTA), epoxy resin, and zinc oxide eugenol- based sealer with single cone obturation techniques using the dye extraction leakage method. Methods: Seventy-five extracted human single-rooted teeth were instrumented using the crown-down technique with the Mtwo rotary file system to file 25/6. The teeth were randomly divided into five experimental groups (n = 15); Group 1 obturated with AH plus, Group 2 obturated with MTA BIOSEAL, Group 3 obturated with Endoseal, Group 4 positive control (POS CTRL) root canals are processed but not obturated, and negative control- apex of teeth completely covered with nail varnish, canals are not treated or obturated. In the first three groups, the single cone obturation technique with gutta-percha 25/6 was used. Apical microleakage was assessed with the dye extraction method, where the absorbance of 2% methylene blue was measured using a spectrophotometer. Results: The mean dye concentration values were MTA 22.79, AH plus 31.16, Endoseal 36.67, POS CTRL 280.15, negative control 9.01. Analysis of variance and pairwise comparisons indicated a significant difference in apical microleakage between the investigated groups (F = 3448, p < 0.001). The MTA BIOSEAL showed significantly less apical microleakage than the AH plus and Endoseal. The AH plus showed less apical microleakage than the Endoseal, although there was no significant difference between these two sealers. Conclusion: With the limitation of the study, it was concluded that MTA sealers show statistically less apical leakage than AH Plus and Endoseal.
Abstract The main non-microbial cause of quality deterioration in lipid-containing food is lipid oxidation, the process in which, simplifying, unsaturated fatty acids react with molecular oxygen via a free radical mechanism. The use of substances with antioxidant properties during the manufacturing process can minimize the extent of lipid oxidation. This research aimed to determine the effect of selected essential oils on the quality and oxidative stability of sunflower oils. Sunflower oils were obtained by refining and cold-pressing and their quality and oxidative stability were studied during the different storage conditions: 20 °C and 5 °C at dark and with light exposure. Obtained results suggested that the antimicrobial and antioxidant properties of essential oils can positively affect the oxidative stability and consequently the quality of sunflower oils during storage, and implicate with further application of essential oils in the edible vegetable oil industry.
Food safety is a story that unites all civilizations, cultures, and nations, and it is interlaced with various methods for making food safer. Concern for nutritious and safe food is as ancient as humankind itself, and many of the food safety issues that persist today are not new. Diverse records from the ancient world, as well as the religious writings of the three monotheist religions, actually refer to food, its intake, and prohibitions, as well as pathological diseases that may follow from inappropriate intake. Over time, food safety has evolved into a scientific discipline concerned with the handling, preparation, transport, and distribution of food to avoid the transmission of illnesses. The current state of food safety knowledge is the result of past discoveries, innovations, and laws. In modern times, the right to consume safe food is a fundamental human right. It contributes to and promotes sustainable development while supporting the economy, trade, and tourism. Nevertheless, despite significant improvements, we still know relatively little about food-borne illnesses and how infections affect humans.
Introduction: Energy drinks (EDs) are products in the form of a beverage or concentrated liquid designed to increase both mental and physical stimulations. Their popularity has grown tremendously, especially among children and adolescents, regardless of the growing number of undesirable health consequences associated with their consumption. This study aimed to evaluate the content of additives in EDs available in the Bosnian and Herzegovinian (B&H) markets. Methods: Twenty-two EDs from 15 brands were analyzed. The contents of quinine (QUIN), caffeine (CAF), benzoic acid (BZA), and sorbic acid (SA) were determined by high-performance liquid chromatography. Results: The median value of QUIN, CAF, SA, and BZA was 0.15 ppm, 309.05 ppm, 75.35 ppm, and 90.80 ppm, respectively. The highest CAF content variation was found in EDs of brand 4, and the lowest was in brand 6. A statistically significant difference was found between the obtained values in relation to the recommended daily intake of CAF for adolescents by the Centers for Disease Control and Prevention and the American Academy of Pediatrics (p < 0.001). Conclusion: The CAF content in EDs deviates by 10% from the content stated in the product declaration. All EDs on the B&H market should carry a clear warning: “High CAF content must not be mixed with alcohol and is not recommended for children, pregnant and/or lactating women, and CAF-sensitive individuals.” Given the behavioral trends associated with the potential risks of excessive CAF consumption, particularly among youth, national agencies in B&H should recognize areas of intervention such as responsible marketing and advertising, and education and awareness-raising. Further research and monitoring would be needed to determine the effectiveness of the various aspects of the proposed risk management approach.
S ciljem zaštite tradicionalne „Visočke pečene janjetine“ oznakom geografskog porijekla pro-vedena su istraživanja na nacionalnom nivou. Po prvi put je detaljno praćen cjelokupni tehnološki po-stupak proizvodnje, od faze iskrvarenja životinje, primarne obrade trupa i konfekcioniranja mesa, do termičke obrade. Osnovni motiv istraživanja bio je ustanoviti autentičnost ovog specifičnog načina ter-mičke obrade janjećeg mesa i njegovu vezu sa ispitivanim područjem (Visoko). Uz navedeno, jedan od ciljeva je bio laboratorijskim ispitivanjima kvantificirati osnovne kvalitativne parametre. Ustanovlje-ni indikatori kvalitete „Visočke pečene janjetine“ poslužit će kao referentni pokazatelji u predstojećim aktivnostima, prilikom utvrđivanja proizvođačke specifikacije. U radu su utvrđivani senzorni, kemijski i mikrobiološki parametri kvalitete „Visočke pečene janjetine“. Senzorna ocjena pokazala je da je kva-liteta Visočke pečene janjetine ekstra visoka, pri čemu je boja najbolje ocijenjeno svojstvo. Srednje vri-jednosti kemijskih parametara iznosile su kako slijedi: 54,18 % vode, masti 19,44 %, proteina 25,28 %, pepela 1,10 %, NaCl 0,20 %. Prosječna pH vrijednost iznosila je 6,47, a aw 0,958.
The unexpected loss of values, as one result of the total destruction during the armed conflicts and war, put us on the challenge to properly decide about methods of rehabilitation, and integrating and understanding values and actions that could vary from restoration to, in many cases, even full reconstruction. During the 1992-1995 war in BiH, many valuable assets of cultural heritage like national monuments, historical places, and historical structures were damaged and/or destroyed. After the aggression, the first step has been to regain and/or establish the function of the places destroyed, while for the cultural heritage assets these attempts called for the approaches more careful. It is not only that the importance or the significance of places and structures destructed is different, the level of destruction also is. These inputs are essential in having preparedness for any action when without possibilities to rely on unique methodology. Even though it is now 20 years after the conflict, Bosnia is still faced with the post-war recovery efforts, with problems newly occurred that are the outcomes of unsuccessfully implemented methods of rehabilitation. This paper aims to present an overview of the interventions implemented within Bosnia and Herzegovina given in respect to the typology of a building, its importance including intangible values and the level of its destruction. Giving examples of Ferhadija/Ferhat Pasha Mosque in Banja Luka and the Old Bridge in Mostar – the examples of total reconstruction, will guide one to understand aspects of choosing the reconstruction action as the appropriate intervention. There are also valuable examples of post-war recovery and rehabilitation for the historical places, such as is the Old town of Počitelj with its entire valuable structures, where after the urban reconstruction – we now have the new challenge of managing the historic place. The inside view shall be more oriented on the case of the Handanija Mosque in Prusac where correct methodology approach had been applied regarding the diagnostic, identifying and/or determining the nature and causes of damage and deterioration of the facility through the inspection and examination, but some rather improper conclusion and decision have been derived from that investigation works. In addition, some analyses of Index of shifts of minaret have been conducted too. Index of shift represents the relation of minaret height – h and width of its layout (D or 2r) or the diameter of circular cross-section. Analyses of conducted work could provide us with a better understanding of the damaged buildings potential weaknesses and weak spots. Reinforcement and strengthening of damaged construction structure has been among the most important tasks. In some cases, improper interventions on heritage structures may have been damaging - in sense of impairing the authenticity, while sometimes it was an insufficient knowledge on structural behaviour and the materials used in historic structures that brought unexpected additional damages. The use of traditional crafts, techniques, and materials is one of the most important elements in the process of architectural heritage protection, contributing to the adequate protection, restoration, conservation, as well as its maintenance.
Old masonry towers, in all their variety – be it a bell tower, a city tower, clock tower, inhabited residential towers, and/or guard/watchtowers – can be found all around the world representing typical urban centre feature, and in some cases –they are the countryside panorama landmark. Statics analysis and calculation are the first steps towards engineering interventions on cultural and historical heritage buildings. In the structural analysis of clock towers, the typical critical points and places where crucial damages that could lead to the collapse, are expected are in the top sections of the building - where the oscillation amplitude reaches its maximal value. Effect on building structure is observed concerning the oscillation frequency and building’s own frequency and energy, which can explain why minaret towers and high slim towers, in some cases, can better withstand earthquakes than extremely rigid buildings; given that the resonance, low-quality materials and other factors can lead to the vulnerability of a building structure. This type of building is designed on a simple, regular shape ground plan, or, in other words, the towers have a symmetrical ground plan and uniformly distributed mass and height. The second statement provides that, depending on building materials used and the cross-section dimensions, towers can be very heavy, which can cause the appearance of significant inertia forces during earthquake oscillations. If there’s mass eccentricity, the horizontal loads could tip the building over. Gradačac clock tower’s load-bearing structural walls are built with masonry stone blocks. The vertical loads are, via slabs and wooden beams, conducted to the walls and down to the foundations. Foundation structure consists of a slab, 80cm thick, positioned at -8.25m which sits on a well-compacted layer of soil. Wooden staircases are used for vertical transportation between storeys. Structural analysis calculation is based on a 3D model of a building and is performed by using the finite elements method (FEM) in Tower calculation software. The requirements for the authenticity in preservation actions imply that the interpretation and the presentation must correlate with basic authenticity principles, in compliance to Nara document (ICOMOS, 1994), protecting cultural values, from both – the hazardous influences of intrusive infrastructure and load of visitors, and incorrect and inappropriate interpretations.
In the protection of historical heritage evaluating the current state of a facility is a very important phase since it provides for the project framework and the decision-making guidelines, which is all crucial for the final goal – protection of Gradačac Old Town complex. There are several historical layers encompassed by Gradačac Old Town - starting from the medieval fortification system, expanding to the Ottomans’ period where main buildings (a residential tower, a clock tower, and a mosque) were added by the Ottomans, extending and continuing the works on adding a library and a gymnasium in the Austro-Hungarian period. The overall Complex flows with the natural morphology of the terrain; nowadays these green areas are used as the main city park. Complex of Gradačac has two separate fortification zones, the main area of around 33 000 m2, and the accentuated part with the tower, of around 3 000 m2. The fortification (The Old Town) ground plan is approximately a square one, with sides from 180 to 200 m, consisting of the two main parts: The Lower and the Upper City. In the north-west area, there’s the Upper City (fortification inside the fortification, namely Husein-Captain Gradaščević’s Tower). The Old Town is accessed through three gates: The North (the main gate), the South, and the West gate. Upper City with Husein-Captain Gradaščević’s tower is positioned on the topmost point in the north side of the fortification complex. It rests on a terrace which encloses it from the south and the east side. On the north side of the Upper City, there are outer perimeter walls constituent to the whole of the Complex. Architectural heritage preservation and valorisation are increasingly important social and economic issue in many countries. The issues encountered in these undertakings range from defining and choosing required level of safety, via the question of electing methodologies relevant for contracting reliable structural analyses and safety check-ups, up to choosing the design and installation of suitable materials, and the intervention.
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