The subject of this research wasto verify the feasibility of implementing green chemistry principles within the business company „Omorika Reciklaža“ Ltd. situated in Johovac near Doboj, Bosnia and Herzegovina. The objective of this study wasto conduct a detailed assessment of the company's facilities and operations, using environmental audits, to identify technological processes (production lines), energy and waste flows, capacities, product range, and other pertinent factors crucial for theapplication of green chemistry principles. Special emphasis was placed on analyzing each substance that constitutes a raw material, whether used individually or as part of mixtures.The assessment of safety data sheets involvedutilizing the CAS registration numbers of substances from the Chemical Abstracts Service, cross-referenced with the ECHA database (European Chemicals Agency). The outcomes, attained through an exhaustive analysis of each substance, were presented as a "chemical inspection" of the company. Through the analysis of all substances and mixtures in the technological process (chemical inspection), as well as the capacity of production flows, energy and resource flows, wastewater, and waste, the potential for enhancing the technological process wasidentified. This involvedreducing dust levels in the workspace, decreasing electricity consumption (utilizing renewable sources), and substituting particularly hazardous chemicals used in the technological process. KEYWORDS:green chemistry; chemical safety; SVHC;environmentalaudit
Waste is a by-product of human activities and living. With the increase in the number of inhabitants, the standard of living and urbanization, the quantities of municipal waste are increasing day by day. Every segment of waste management starting from generation, through collection, storage, transport, treatment and disposal can pose a potential hazard to human health and the environment. Waste management in Republic of Srpska is organized at the regional level. Since only waste disposal is still present in the Republic of Srpska, the regional approach implies that there is a landfill on the territory of one of the local self-government units, where all local self-government units in the region dispose of waste. In addition, waste disposal in illegal and unregulated landfills is still evident. LGUs or utility companies often face a lack of money to organize waste collection, with the result that not all households are covered by waste collection. In recent years, a lot has been invested in infrastructure, such as the filling of containers and containers and the purchase of new or newer used waste collection vehicles. Future directions of improving the waste management system in Republic of Srpska must go in the direction of sustainable waste management, ie waste management in a way to reduce the negative impact on human health and the environment, as well as avoiding leaving this problem to future generations.
Waste disposal is just one of the segments in solid municipal waste management system. During the entire life cycle of waste, starting from waste generation, through storage, collection, transport, recycling, treatment and disposal, several different pollutants are emitted. By disposing solid waste, non-road mobile machinery (NRMM) emits various pollutants into the air such as CO2, CO, NMVOC, PM, PAHs, heavy metals, etc. These substances can pose certain problems for human health and the environment. The subject of this study is the calculation of air emissions of CO2, CH4, N2O, NMVOC, PM10, CO, Cd, Cr and PAHs (chrysene and benz[a]anthracene) from NRMM which are included in the activities of receiving and disposing of waste at the Banja Luka landfill. The study evaluates the emission of pollutants using the EEA guidelines for the assessment of the emission of pollutants into the air, based on the consumption of diesel fuel during the year. This study, which is based on the calculation of NRMM emissions at the Banja Luka landfill, should serve as an example not only to other landfills but also to sectors that use NRMM on the importance of keeping track of pollutant emissions. The goal is to look at these emissions and introduce changes and improvements in this sector by replacing old NRMMs with new ones, optimizing operation, using diesel of satisfactory quality, etc.
Abstract Waste transport is just one of the segments in the solid municipal waste management. Throughout the entire waste life cycle, starting by generation of waste, via storing, collecting, transporting, recycling, treating and depositing, several different polluting substances are emitted. The solid waste transport, apropos, transporting vehicles emit into the air different pollution substances such as CO2, CO, NOx, NMVOC, PM, PAHs etc. These substances can present certain problems for human health and environment. The research subject of this study is the analysis of solid waste transportation within the Banja Luka region (B&H), from towns and municipalities belonging to the region and transporting their mixed municipal waste to the Banja Luka landfill. In the analysis, following parameters are included: distance to the landfill, type of vehicle used for the waste transportation, type of the engine, vehicle capacity and the number of tours during a year. The study estimates the emission of CO, NOx, NMVOC, and PM2.5 during one year using the listed parameters and by applying EMEP/EEA guidelines for estimating the emission of polluting substances into the air. The largest emission of polluting substances (CO, NOx, NMVOC and PM2.5) is from the oldest vehicles. The newest vehicles had a significantly lesser emission of these polluting substances into the air. The recommendation for decreasing the emission from the transportation vehicles is to organise the transfer-stations, procure new vehicles, optimise the collection routes and decrease the number of tours, as well as to better the usage of the vehicle capacity level.
: Chromium in wastewater is discharged from tannery, electroplating, metal finishing, dying industry and many other industries. Presence of hexavalent chromium (Cr(VI)) in the environment considerable concern because it is non-biodegradable, highly toxic and carcinogen. There are several treatments for the removal of chromium from wastewater, but the most common method involves reduction to its less toxic trivalent state. In this paper electrocoagulation was used as treatment for removing of hexavalent chromium from synthetic prepared wastewater initial concentration 50 mg/L, in presence of sodium chloride as supporting electrolyte (1 g/L). The treatment was perform in a batch electrochemical reactor 250 mL capacity and with possibility of constant stirring. It was examined the impact of electrode materials and current density (5, 10, 20 mA/cm 2 ) on Cr(VI) removal efficiency. The examination showed that iron has higher removal efficiency compared to aluminium. Also, it was observed high efficiency at very begin of treatment and at low current density. For 20 minutes of treatment it was achieved almost complete Cr(VI) removal at current density of 5 mA/cm 2 by using iron electrodes ( E= 99.8 %).
The main objectives of waste management are environmental preservation, the safeguarding of human health, and natural resources conservation. Material flow analysis/ substances flow analysis (MFA/SFA) method takes into account the consideration of the “metabolic” system of waste management, which means monitoring waste flows and substances within the model for waste management, and examining all inputs and outputs in the system, as well as their evaluation and comparison. Modeled scenarios in the Banjaluka region of the Republic of Srpska (RS) were developed in accordance with both the European Union (EU) and RS legislation, as well as relevant municipal waste management strategic documents. Modeled municipal solid waste (MSW) management scenarios are compared with the current waste management system. Using MFA/SFA (waste flow, carbon, and nitrogen), a complete view of flow, transformations, and final waste disposal and substances in modeled scenarios of waste management is realized. Results of this study suggest that in the future, more activity should be based on the separate collection and recycling, compared to the current, inadequate MSW management system that is based only on the disposal of waste. The combination of material and substance flows analyses is an effective tool in the decision-making process for the development and improvement of MSW management.
In this paper life cycle assessment was applied to analyze and evaluate, from an environmental point of view, current and alternatives to the current solid waste management system in Banjaluka region. The current system, which is disposal on landfill, has significant adverse environmental impacts caused by methane emissions from landfill. Therefore, four different scenarios were developed as alternatives to the current waste management system. Landfilling with energy recovery, separate collection of packaging waste, incineration and anaerobic digestion were considered in these scenarios. The functional unit in this study is 100,000 tons which is the amount of municipal waste which is generated within one year in Banjaluka. The assessment in this study was based on results from modelling performed in the EASETECH model. The improvement of gas collection in the current scenario and its utilisation for the purpose of creating energy will have a positive effect on the environment. Increasing separation collection of packaging waste and reducing biodegradable waste will have a positive effect on the environment. The separation and recycling of packaging waste should begin as soon as possible and policies that promote source separated collection should be implemented.
Reducing of environmental pollution can bring off only initiation improvement in technical process. Measures of improvement which are suggested in this work are replacement cyanides electrolytes for electrodeposition of zinc coatings with alkaline electrolytes without cyanides or acid electrolytes. Special attention has given on questions and problems purification waste waters from zink bath.
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